Laboratory Products
Developing a New Solution for Nuclear Waste Disposal
May 04 2016
Two Carbolite MTT furnaces specially designed for extracting carbon-14 and fixed tritium are being used by the Nuclear Graphite Research Group (NGRG) at the University of Manchester in a project to develop new nuclear waste disposal procedures.
If the UK's current nuclear reactors operate to their proposed shutdown dates, approximately 100,000 tonnes of nuclear grade graphite will require disposal. This graphite would be considered as intermediate level waste (ILW). The current strategy for storing this material is long-term deep burial in a geological disposal facility (GDF) - a costly and time-consuming procedure.
Each nuclear reactor typically contains at least 2000 tonnes of nuclear graphite in the form of large blocks. Reducing this volume by gasification is the aim of the research project at the NGRG. The Carbolite furnaces are being used to determine at laboratory scale the optimum specifications for this procedure, including the dimensions of the material to be processed and the temperatures, time and oxygen concentrations required.
Cubes of nuclear-grade graphite are first size-reduced into particulate form before being placed into ceramic boats and heated in the furnaces. At high temperatures oxygen is passed through the furnaces, leading to oxidation of the graphite and the production of CO and CO2. These gaseous releases can then be monitored through mass spectroscopy
The furnaces use catalyst-assisted combustion techniques to extract the carbon-14 and organically bound tritium cleanly and precisely and without contamination of scintillation media. A specially designed manifold optimises catalyst performance. Sample capacities up to 20ml provide accurate determinations in the 38mm-diameter quartz glass work-tube assemblies. The heated length of the furnaces is 850mm and maximum temperature 1200ºC, with both heating zones in each unit having over-temperature protection.
The Carbolite units have 20-segment programmable temperature controllers for sample-specific combustion protocols, as well as sophisticated data storage and communications.
Digital Edition
Lab Asia 31.2 April 2024
April 2024
In This Edition Chromatography Articles - Approaches to troubleshooting an SPE method for the analysis of oligonucleotides (pt i) - High-precision liquid flow processes demand full fluidic c...
View all digital editions
Events
Apr 25 2024 Istanbul, Turkey
Apr 28 2024 Montreal, Quebec, Canada
May 05 2024 Seville, Spain
InformEx Zone at CPhl North America
May 07 2024 Pennsylvania, PA, USA
May 14 2024 Oklahoma City, OK, USA